Kierownik zespołu
Prof. Daniel Gryko

Adiunkci
Dr Beata Koszarna
Dr Yevgen Poronik
Dr Mariusz Tasior
Dr Olena Vakuliuk

Asystenci
Dr Łukasz Kielesiński
Dr Maciej Krzeszewski
Dr Damian Kusy
Dr Bartłomiej Sadowski
Dr Kamil Skonieczny
Mgr Krzysztof Górski
Mgr Krzysztof Gutkowski

Doktoranci
Mgr Gana Sanil
Mgr Dinesh Kumar Ganga Reddy
Mgr Jaqueline Stella Badaro Araujo
Mgr Kateryna Vygranenko
Mgr Paula Garbacz
Mgr Jakub Wagner

Publikacje

M. Tasior, P. Gajewski, O. Vakuliuk, D. T. Gryko, „Novel donor-acceptor systems bearing an isoxazol-5-one core”, Arkivoc

R. Orłowski, J. A. Clark, J. B. Derr, E. M. Espinoza, M. F. Mayther, O. Staszewska-Krajewska, J. R. Winkler, H. Jędrzejewska, A. Szumna, H. B. Gray, V. I. Vullev, D. T. Gryko, „Role of intramolecular hydrogen bonds in promoting electron flow through amino acid and oligopeptide conjugates”, Proc. Nat. Acad. Sci. U. S. A.

G. D. Kumar, M. Banasiewicz, D. Jacquemin, D. T. Gryko, „Switch‐On Diketopyrrolopyrrole‐Based Chemosensors for Cations Possessing Lewis Acid Character”, Chem. Asian J.

J. A. Clark, R. Orłowski, J. B. Derr, E. M. Espinoza, D. T. Gryko, V. I. Vullev, „How does tautomerization affect the excited-state dynamics of an amino acid-derivatized corrole?”, Photosynth. Res.

A. Friedman, N. R. Samala, H. C. Honig, M. Tasior, D. T. Gryko, L. Elbaz, I. Grinberg, „Control of Molecular Catalysts for Oxygen Reduction by Variation of pH and Functional Groups”, ChemSusChem

Ł. Kielesiński, O. Morawski, C. Barboza, D. T. Gryko, „Polarized Helical Coumarins: [1,5] Sigmatropic Rearrangement and Excited-State Intramolecular Proton Transfer”, J. Org. Chem.

M. Krzeszewski, Ł. Dobrzycki, A. Sobolewski, M. Cyrański, D. T. Gryko, „Bowl‐Shaped Pentagon‐ and Heptagon‐Embedded Nanographene Containing a Central Pyrrolo[3,2‐ b ]pyrrole Core”, Angew. Chem. Int. Ed.

M. Jacquet, M. Izzo, S. Osella, S. Kozdra, P. P. Michałowski, D. Gołowicz, K. Kazimierczuk, M. T. Gorzkowski, A. Lewera, M. Teodorczyk, B. Trzaskowski, R. Jurczakowski, D. T. Gryko, J. Kargul, „Development of a universal conductive platform for anchoring photo- and electroactive proteins using organometallic terpyridine molecular wires”, Nanoscale

D. M. Andrada, C. Foroutan-Nejad, „Energy components in energy decomposition analysis (EDA) are path functions; why does it matter?”, Phys. Chem. Chem. Phys.

Y. Poronik, G. V. Baryshnikov, I. Deperasińska, E. M. Espinoza, J. A. Clark, H. Ågren, D. Gryko, V. I. Vullev, „Deciphering the unusual fluorescence in weakly coupled bis-nitro-pyrrolo[3,2-b]pyrroles”, Commun. Chem.

Ł. Łukasiewicz, M. Rammo, C. Stark, M. Krzeszewski, D. Jacquemin, A. Rebane, D. T. Gryko, „Ground‐ and Excited‐State Symmetry Breaking and Solvatofluorochromism in Centrosymmetric Pyrrolo[3,2‐ b ]pyrroles Possessing two Nitro Groups”, ChemPhotoChem

K. Gutkowski, K. Skonieczny, M. Bugaj, D. Jacquemin, D. T. Gryko, „N‐Arylation of Diketopyrrolopyrroles with Aryl Triflates”, Chem. Asian J.

O. Morawski, D. T. Gryko, A. Sobolewski, Ł. Kielesiński, „Highly Polarized Coumarin Derivatives Revisited: Solvent-controlled Competition Between Proton Coupled Electron Transfer and Twisted Intramolecular Charge Transfer”, Chem. Eur. J.

A. Minotto, P. A. Haigh, Ł. Łukasiewicz, E. Lunedei, D. T. Gryko, I. Darwazeh, F. Cacialli, „Visible light communication with efficient far-red/near-infrared polymer light-emitting diodes”, Light-Sci. Appl.

P.-T. Chou, S.-M. Tseng, F. Ambicki, I. Deperasińska, D. T. Gryko, Y. Poronik, „How an Eight-Membered Ring Alters the Rhodamine Chromophore”, J. Org. Chem.

Y. Qin, C. Schnedermann, M. Tasior, D. T. Gryko, D. G. Nocera, „Direct Observation of Different One- and Two-Photon Fluorescent States in a Pyrrolo[3,2-b]pyrrole Fluorophore”, J. Phys. Chem. Lett.

K. Skonieczny, I. Papadopoulos, D. Thiel, K. Gutkowski1, P. Haines, P. M. McCosker, A. D. Laurent, P. A. Keller, T. Clark, D. Jacquemin, D. M. Guldi, D. T. Gryko, „How To Make Nitroaromatic Compounds Glow: Next‐Generation Large X‐Shaped, Centrosymmetric Diketopyrrolopyrroles”, Angew. Chem. Int. Ed.

A. Nowak-Król, B. Koszarna, M. Krzeszewski, T. D. Lohrey, J. Arnold, D. T. Gryko, „Access to Corrole-Appended Persubstituted Benzofurans by a Multicomponent Reaction: The Dual Role of p-Chloranil”, Org. Lett.

M. Tasior, O. Vakuliuk, D. Koga, B. Koszarna, K. Górski, M. Grzybowski, Ł. Kielesiński, M. Krzeszewski, D. T. Gryko, „Method for the Large-Scale Synthesis of Multifunctional 1,4-Dihydro-pyrrolo[3,2-b]pyrroles” J. Org. Chem.

M. Grzybowski, B. Sadowski, H. Butenschön, D. T. Gryko, „Synthetic Applications of Oxidative Aromatic Coupling – from Biphenols to Nanographenes”, Angew. Chem. Int. Ed.

D. C. Young, M. Tasior, A. D. Laurent, Ł. Dobrzycki, M. K. Cyrański, N. Tkachenko, D. Jacquemin, D. T. Gryko, „Photostable orange-red fluorescent unsymmetrical diketopyrrolopyrrole–BF2 hybrids”, J. Mater. Chem. C

Z. Szakács, M. Tasior, D. T. Gryko, E. Vauthey, „Change of Quadrupole Moment upon Excitation and Symmetry Breaking in Multibranched Donor‐Acceptor Dyes”, ChemPhysChem

T. Kim, W. Kim, O. Vakuliuk, D. T. Gryko, D. Kim, „Two-Step Charge Separation Passing Through the Partial Charge-Transfer State in a Molecular Dyad”, J. Am. Chem. Soc.

M. Pieczykolan, J.Czaban-Jóźwiak, M. Malinska, K. Woźniak, R. Dorta, A. Rybicka, A. Kajetanowicz, K. Grela, „The Influence of Various N-Heterocyclic Carbene Ligands on Activity of Nitro-Activated Olefin Metathesis Catalysts”, Molecules

M. Pieczykolan, B. Sadowski, D. T. Gryko, „An Efficient Method for the Programmed Synthesis of Multifunctional Diketopyrrolopyrroles”, Angew. Chem. Int. Ed.

J. Lewtak, B. Koszarna, M. Charyton, D. T. Gryko, „Extending a porphyrin chromophore via fusion with naphthalene”, J. Porphyr. Phthalocya.

S. Hatanaka, T. Ono, Y. Yano, D. T. Gryko, Y. Hisaeda, „Tris(pentafluorophenyl)borane-pyrrolo[3,2-b]pyrrole Hybrids: Solid-State Structure and Crystallization-Induced Enhanced Emission”, ChemPhotoChem

B. Sadowski, D. Stewart, A. Phillips, T. Grusenmeyer, J. Haley, T. Cooper, D. T. Gryko, „From Dipyrrolonaphthyridinediones to Quinazolinoindolizinoindolizinoquinazolines”, J. Org. Chem.

I. Benkyi, O. Staszewska-Krajewska, D. T. Gryko, M. Jaszuński, A. Stanger, D. Sundholm, „The Interplay of Aromaticity and Antiaromaticity in N-Doped Nanographenes”, J. Phys. Chem. A

M. K. Węcławski, I. Deperasińska, M. Banasiewicz, D. C. Young, A. Leniak, D. T. Gryko, „Building Molecular Complexity from Quinizarin; Conjoined Coumarins and Coronene Analogs”, Chem. Asian J.

M. Banasiewicz, R. Stężycki, G. D. Kumar, M. Krzeszewski, M. Tasior, B. Koszarna, A. Janiga, O. Vakuliuk, B. Sadowski, D. T. Gryko, D.Jacquemin, „Electronic Communication in Pyrrolo[3,2-b]pyrroles Possessing Sterically Hindered Aromatic Substituents”, Eur. J. Org. Chem.

K. Kielesiński, O. W. Morawski, A. L. Sobolewski, D. T. Gryko, „The synthesis and photophysical properties of tris-coumarins”, Phys. Chem. Chem. Phys.

E. M. Espinoza, D. Bao, M. Krzeszewski, D. T. Gryko, V. I. Vullev, „Is It Common for Charge Recombination to Be Faster than Charge Separation?”, Int. J. Kin.

R. Orłowski, G. Cichowicz, O. Staszewska-Krajewska, W. Schilf, M. K. Cyrański, D. T. Gryko, „Covalently Linked Bis(Amido-Corroles): Inter- and Intramolecular Hydrogen Bond Driven Supramolecular Assembly”, Chem. Eur. J.

M. Tasior, B. Koszarna, D. C. Young, B. Bernard, D. Jacquemin, D. Gryko, D. T.Gryko, „Fe(III)-catalyzed synthesis of pyrrolo[3,2-b]pyrroles: formation of new dyes and photophysical studies”, Org. Chem. Front.

Y. Yano, T. Ono, S. Hatanaka, D. T. Gryko, Y. Hisaeda, „Salt–cocrystal continuum for photofunction modulation: stimuli-responsive fluorescence color-tuning of pyridine-modified intramolecular charge-transfer dyes and acid complexes”, J. Mater. Chem. C

D. Perevoznik, R. Nazir, R. Kiyan, K. Kurselis, B. Koszarna, D. T. Gryko, B. N. Chichkov, „High-speed two-photon polymerization 3D printing with a microchip laser at its fundamental wavelength”, Optics Express

B. Sadowski, D. J. Stewart, A. T. Phillips, T. A. Grusenmeyer, J. E. Haley, T. M. Cooper, D. T. Gryko, „From Dipyrrolonaphthyridinediones to Quinazolinoindolizinoindolizinoquinazolines”, J. Org. Chem.

B. Bardi, M. Krzeszewski, D. T. Gryko, A. Painelli, F. Terenziani, „Excited-State Symmetry Breaking in an Aza-Nanographene Dye”, Chem. Eur. J.

K. Kielesiński, D. T. Gryko, A. L. Sobolewski, O. Morawski, „Interplay Between Solvation and Stacking of Aromatic Rings Governs Bright and Dark Sites of Benzo[g]coumarins”, Chem. Eur. J.

O. Vakuliuk, Y. W. Jun, K. Vygranenko, G. Clermont, Y. J. Reo, M. Blanchard-Desce, K. H. Ahn, D. T. Gryko, „Modified Isoindolediones as Bright Fluorescent Probes for Cell and Tissue Imaging”, Chem. Eur. J.

M. Grzybowski, B. Sadowski, H. Butenschön, D. T. Gryko, „Synthetic Applications of Oxidative Aromatic Coupling – from Biphenols to Nanographenes”, Angew. Chem. Int. Ed.

Y. M. Poronik, K. V. Vygranenko, D. Gryko, D. T. Gryko, „Rhodols – synthesis, chemical and optical properties and applications as fluorescent probes”, Chem. Soc. Rev.

M. Tasior, G. Clermont, M. Blanchard-Desce, D. Jacquemin, D. T. Gryko, „Synthesis of Bis(arylethynyl)pyrrolo[3,2-b]pyrroles and Effect of Intramolecular Charge Transfer on Their Photophysical Behavior”, Chem. Eur.J.

H. Honig, C. Krishnamurthy, I. Borge-Durán, M. Tasior, D. Gryko, I. Grinberg, L. Elbaz, „Structural and Physical Parameters Controlling the Oxygen Reduction Reaction Selectivity with Carboxylic Acid-Substituted Cobalt Corroles Incorporated in a Porous Carbon Support”, J. Phys. Chem. C

S. E. Kutniewska, K. N. Jarzembska, R. Kamiński, A. J. Stasyuk, D. T. Gryko, M. K. Cyrański, „Structural, energetic and spectroscopic studies of new luminescent complexes based on 2-(2′-hydroxyphenyl)­imidazo[1,2-a]pyridines and 1,2-phenylenediboronic acid”, Acta Cryst.

C.-S. Hsu, M. K. Węcławski, B. Koszarna, D. T. Gryko, H. M. Chen, „π-Conjugated Organic/Inorganic Hybrid Photoanodes: Revealing the Photochemical Behavior through in-situ X-ray Absorption Spectroscopy”, Chem. Eur. J.

B. Sadowski, S.-H. Su, T.-C. Lin, T. D. Lohrey, I. Deperasińska, P.-T. Chou, D. T. Gryko, „The influence of tetraphenylethylene moieties on the emissive properties of dipyrrolonaphthyridinediones”, J. Mat. Chem. C

B. Sadowski, M. Loebnitz, D. Dombrowski, D. H. Friese, D. T. Gryko, „Electron-Rich Dipyrrolonaphthyridinediones – Synthesis and Optical Properties”, J. Org. Chem.

M. Tasior, K. Hassanein, L. M. Mazur, I. Sakellari, D. Gray, M. Farsari, M. Samoć, F. Santoro, B. Ventura, D. T. Gryko, „The role of intramolecular charge transfer and symmetry breaking in the photophysics of pyrrolo[3,2-b]pyrrole-dione”, Phys. Chem. Chem. Phys.

R. Stężycki, D. Reger, H. Hoelzel, N. Jux, D. T. Gryko, „Synthesis and Photophysical Properties of Hexaphenylbenzene-pyrrolo[3,2-b]pyrroles”, Synlett

M. K. Węcławski, I. Deperasińska, M. Banasiewicz, D. C. Young, A. Leniak, D. T. Gryko, „Building Molecular Complexity from Quinizarin: Conjoined Coumarins and Coronene Analogs”, Chem. Asian J.

B.Sadowski, K. Hassanein, B. Ventura, D. T. Gryko, „Tetraphenylethylenepyrrolo[3,2-b]pyrrole Hybrids as Solid-State Emitters: The Role of Substitution Pattern”, Org. Lett.

M. Krzeszewski, E. M. Espinoza, C. Červinka, J. B. Derr, J. A. Clark, D. Borchardt, G. J. O. Beran, D. T. Gryko, V. I. Vullev, „Dipole Effects on Electron Transfer are Enormous”, Angew. Chem. Int. Ed.

Ł. Kielesiński, D. T. Gryko, A. L. Sobolewski, O. W. Morawski, „Effect of conformational flexibility on photophysics of bis-coumarins”, Phys. Chem. Chem. Phys.

S. Mishra, M. Krzeszewski, C. A. Pignedoli, P. Ruffieux, R. Fasel, D. T. Gryko, „On-surface Synthesis of a Nitrogen-Embedded Buckybowl with Inverse Stone-Thrower-Wales Topology”, Nature Commun.

M. Krzeszewski, K. Sahara, Y. M. Poronik, T. Kubo, D. T. Gryko, „Unforeseen 1,2-Aryl Shift in Tetraarylpyrrolo[3,2-b]pyrroles Triggered by Oxidative Aromatic Coupling”, Org. Lett.

K. Gutkowski, C. Azarias, M. Banasiewicz, B. Kozankiewicz, D. Jacquemin, D. T. Gryko, „Synthesis and Photophysical Properties of N-arylated Diketopyrrolopyrroles”, Eur. J. Org. Chem.

M. Tasior, M. Czichy, M. Łapkowski, D. T. Gryko, „Dibenzothieno-pyrrolo[3,2-b]pyrrole – the missing member of thienoacenes family”, Chem. Asian J.

H. G. Ryu, M. F. Mayther, J. Tamayo, C. Azarias, E. M. Espinoza, M. Banasiewicz, Ł. G. Łukasiewicz, Y. M. Poronik, A. Jeżewski, J. Clark, J. B. Derr, K. H. Ahn, D. T. Gryko, D. Jacquemin, V. I. Vullev, „Bidirectional Solvatofluorochromism of a Pyrrolo[3,2-b]pyrrole-diketopyrrolopyrrole Hybrid”, J. Phys. Chem. C

B. Sadowski, M. F. Rode, D. T. Gryko, „Direct Arylation of Dipyrrolonaphthyridinediones (DPNDs) Leads to Red-Emitting Dyes with Conformational Freedom”, Chem. Eur. J.

Y. M. Poronik, T. Bernaś, A. Wrzosek, M. Banasiewicz, A. Szewczyk, D. T. Gryko, „One‐Photon and Two‐Photon Mitochondrial Fluorescent Probes Based on a Rhodol Chromophore”, Asian J. Org. Chem.

J. Lewtak, M. Stillman, B. Koszarna, D. Koszelewski, C. Levy, D. Gryko, „Differential quenching of the angular momentum of the B and Q bands of a porphyrin as a result of extended ring π-conjugation”, Journal of Porphyrins and Phthalocyanines

B. Dereka, A. Rosspeintner, R. Stężycki, C. Ruckebusch, D. T. Gryko, E. Vauthey, „Excited-State Symmetry Breaking in a Quadrupolar Molecule Visualized in Time and Space”, J. Phys. Chem. Lett.

O. Vakuliuk, S. Ooi, I. Deperasińska, O. Staszewska-Krajewska, M. Banasiewicz, B. Kozankiewicz, O. Danylyuk, D. T. Gryko, „Unprecedented rearrangement of diketopyrrolopyrroles leads to structurally unique chromophores”, Chem. Comm.

E. M. Espinoza, J. M. Larsen-Clinton, M. Krzeszewski, N. Darabedian, D. T. Gryko, V. I. Vullev, „Bioinspired approach toward molecular electrets: synthetic proteome for materials”, Pure Appl. Chem.

M. K. Węcławski, M. Jakešová, M. Charyton, N. Demitri, B. Koszarna, K. Oppelt, S. Sariciftci, D. T. Gryko, E. D. Głowacki, „Biscoumarin-containing acenes as stable organic semiconductors for photocatalytic oxygen reduction to hydrogen peroxide”, J. Mat. Chem. A

M. Krzeszewski, D. Gryko, D. T. Gryko, „The Tetraarylpyrrolo[3,2-b]pyrroles – From Serendipitous Discovery to the Promising Heterocyclic Optoelectronic Material”, Acc. Chem. Res.

B. Sadowski, H. Kita, M. Grzybowski, K. Kamada, D. T. Gryko, „π-Expanded Dipyrrolonaphthyridinediones with Large Two-Photon Absorption Cross-Section Values”, J. Org. Chem.

K. Skonieczny, J. Jaźwiński, D. T. Gryko, „The synthesis of imidazo[1,2-f]phenanthridines, phenanthro[9,10-d]imidazoles and phenanthro[9′,10′:4,5]imidazo[1,2-f]phenanthridines via intramolecular oxidative aromatic coupling”, Synthesis

R. Orłowski, M. Tasior, O. Staszewska-Krajewska, Ł. Dobrzycki, W. Schilf, B. Ventura, M. K. Cyrański, D. T. Gryko, „Hydrogen Bond Involving Cavity NH Protons Drives Supramolecular Oligomerization of Amido-Corroles”, Chem. Eur. J.

Ł. Kielesiński, O. Morawski, Ł. Dobrzycki, A. L. Sobolewski, D. T. Gryko, „The Coumarin-Dimer Spring – The Struggle Between Charge Transfer and Steric Interactions”, Chem. Eur. J.

E. Harputlu, K. Ocakoglu, F. Yakuphanoglu, A. Tarnowska, D. T. Gryko, „Physical properties of self-assembled zinc chlorin nanowires for artificial light-harvesting materials”, Nano-Structures & Nano-Objects

Ł. G. Łukasiewicz, H. G. Ryu, A. Mikhaylov, C. Azarias, M. Banasiewicz, B. Kozankiewicz, K. H. Ahn, D. Jacquemin, A. Rebane, D. T. Gryko, „Symmetry Breaking in Pyrrolo[3,2-b]pyrroles: Synthesis, Solvatofluorochromism and Two-photon Absorption”, Chem. Asian J.

Y. Poronik, L. Mazur, M. Samoć, D. Jacquemin, D. T. Gryko, „2,5-Bis(azulenyl)pyrrolo[3,2-b]pyrroles the key influence of the linkage position on the linear and non-linear optical properties”, J. Mat. Chem. C

A. Purc, B. Koszarna, I. Iachina, D. H. Friese, M. Tasior, K. Sobczyk, T. Pedzinski, J. Brewer, D. T. Gryko, „The impact of interplay between electronic and steric effects on the synthesis and the linear and non-linear optical properties of diketopyrrolopyrroles bearing benzofuran moieties”, Org. Chem. Front.

O. Vakuliuk, A. Purc, G. Clermont, M. Blanchard-Desce, D. T. Gryko, „The Impact of the Interplay between Steric and Electronic Effects on the Synthesis and the Optical Properties of Diketopyrrolopyrroles bearing Pyridine Moieties”, Chem. Photo. Chem.

M. Santra, Y. W. Jun, J. Bae, S. Sarkar, W. Choi, D. T. Gryko, K. H. Ahn, „Water-soluble pyrrolo[3,2-b]pyrroles: synthesis, their luminescence and two-photon cellular imaging properties”, Asian J. Org. Chem.

B. Dereka, A. Rosspeintner, M. Krzeszewski, D. T. Gryko, E. Vauthey, „Symmetry-Breaking Charge Transfer and Hydrogen Bonding: Toward Asymmetrical Photochemistry”, Angew. Chem., Int. Ed.

R. Orłowski, D. Gryko, D. T. Gryko, „Synthesis of Corroles and Their Heteroanalogs”, Chem. Rev.

M. Grzybowski, E. Głodkowska-Mrówka, G. Clermont, M. Blanchard-Desce, D. T. Gryko, „The Synthesis and Optical Properties of Water Soluble Diketopyrrolopyrroles”, Chem. Het. Comp.

tematyka badań

  • Synteza nowych barwników funkcjonalnych
  • Absorpcja dwufotonowa
  • Wewnątrzcząsteczkowe przeniesienie protonu w stanie wzbudzonym
  • Opracowywanie fluoroforów do obrazowania optycznego
  • Silnie emitujące heliceny